
Statement: For a fixed amount of gas at constant temperature, the absolute pressure is inversely proportional to the volume.
PโVโ = PโVโ โ P ร V = constant (k)
Mathematical Derivation: From Ideal Gas Law PV = nRT, if T and n are constant, then PV = constant. Therefore, P โ 1/V.
Molecular Interpretation: When volume decreases, gas particles collide with walls more frequently, increasing pressure. The P-V graph is a rectangular hyperbola.
๐ Graphical Forms:
- P vs V : Hyperbola (P = k/V)
- P vs 1/V : Straight line through origin
- log P vs log V : Straight line slope -1
๐ฌ Experimental Verification:
Using a J-tube and mercury column, volume changes inversely with applied pressure.
๐งช Formula Summary: PโVโ = PโVโ | k = nRT | At constant T, Pโ = Pโ ร (Vโ/Vโ)
๐ Real-world Applications: Syringes, breathing mechanism, scuba diving (pressure affects lung volume), bicycle pumps.
Volume (V)
10.0 L
Pressure (P)
1.00 atm
Boyle's Law: P ร V = k
1.00 ร 10.0 = 10.0
Pressure vs Volume โ Hyperbolic curve (P = k/V)
Pressure vs 1/Volume โ Straight line (Proof)
| Volume (L) | Pressure (atm) | P ร V |
|---|